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71.
《International Journal of Hydrogen Energy》2020,45(16):9854-9864
In hexagonal close-packed titanium, the interactions between the twin boundary (TB) and hydrogen solute atoms with several different concentrations are investigated by using first-principles calculations. The preferential occupation sites of hydrogen atoms in the TB region are searched and vary with the amount of hydrogen. Both the shift of the TB and the diffusion of hydrogen atoms, as well as the mutual effect on the movement of each other, are studied. The energy barriers of the TB shift increase with the hydrogen concentration. Additionally, the simulated tensile tests are applied for several systems with co-existing TB and hydrogen atoms, and different geometry transformation behaviors at different hydrogen concentrations are found under the increasing tensile strain. 相似文献
72.
《Journal of the European Ceramic Society》2020,40(15):5819-5828
In this paper, a novel Dy2O3-Al2O3-SiO2 (DAS) glass ceramic was designed and prepared for joining zirconia toughened alumina (ZTA) ceramic. The crystallization, thermal expansion behavior and wetting behavior of the DAS glass filler were studied. The effect of cooling rate and joining temperature on the microstructure and flexural strength of joints was investigated. The results show that slow cooling rate (15 °C/min) leads to crystallization of brazing seam, which causes the formation of pores in the joints due to the large density difference between the glass and the crystalline phases. The dissolution of ZrO2 from ZTA substrate into the filler during joining process improves the mismatch of the coefficient of thermal expansion (CTE) between the brazing seam and substrate. The maximum flexural strength of 535 MPa is obtained when the joining temperature and cooling rate are 1475 °C and 50 °C/min, respectively. 相似文献
73.
相对于传统热轧、温轧、冷轧,深冷轧制是一项变革性技术,它利用某些金属材料在深冷情况下具有优异的塑性变形能力以及深冷环境阻碍塑性变形过程中位错运动和再结晶行为,促使材料晶粒细化,材料具有更高的强度与韧性。系统地介绍了近年来深冷轧制制备高性能金属材料的研究进展,包括深冷轧制在铝合金、铜合金、钛合金、复合层状金属带材中的应用。对深冷轧制制备高性能金属材料的研究进行了展望。 相似文献
74.
75.
设计3种不同再生骨料取代率的再生混凝土立方体试件,分别在7 d、14 d、28 d、100 d龄期进行抗压强度试验,结果表明:长龄期再生混凝土立方体抗压强度有所增大,但高取代率比低取代率的抗压强度降低,再生混凝土后期强度增长速率高于普通混凝土。对试验室实测的再生混凝土立方体抗压强度与试验龄期进行拟合,拟合结果相关系数均大于0.97,吻合结果较好。 相似文献
76.
以OMS-2粉体催化剂为基础,对催化剂进行挤出成型,考察粘结剂种类、粘结剂用量、润滑剂和孔结构改进剂用量、焙烧温度对成型催化剂机械强度的影响。得到最佳成型工艺条件为,粘结剂硅溶胶用量为OMS-2粉体催化剂质量的105%~110%、辅助粘结剂纳米ZrO_2用量为OMS-2粉体催化剂质量的30%~35%、润滑剂田菁粉用量为OMS-2粉体催化剂质量的2. 5%~3. 0%、孔结构改进剂柠檬酸用量为OMS-2粉体催化剂质量的5%~6%,焙烧温度450℃。成型后催化剂机械强度可达150 N·cm~(-1),满足工业化应用对催化剂强度的要求。将成型催化剂应用于催化湿式氧化印染废水处理,经过432 h活性评价时间,COD平均去除率约91. 6%,反应结束后催化剂结构完整,平均机械强度约144 N·cm~(-1),表现出良好的水热稳定性。 相似文献
77.
为探究大水矿山充填体的力学性能变化,将充填体试块置入高压水体中使其内部形成孔隙水压,研究孔隙水压下充填体的抗压强度、抗拉强度和含水量等指标的变化。试验以孔隙水压、浸入时间、充填配比和料浆浓度为主要影响因素,开展29组充填体强度试验。方差分析表明,料浆浓度和充填配比对充填体抗压强度影响极显著,孔隙水压影响显著;浸入时间对充填抗拉强度影响显著。相同充填配比和料浆浓度下的充填体抗压和抗拉强度随孔隙水压和浸入时间增长而下降,其中抗拉强度下降幅度较大。充填体含水量随孔隙水压增大而增大,增长趋势和充填体强度增大趋势相吻合。 相似文献
78.
79.
Jianhao Liu Zhou Hu Yuxia Zhang 《International Journal of Applied Ceramic Technology》2020,17(3):886-892
Dynamic indirect tension experiments were performed on zirconium diboride-silicon carbide (ZrB2−20%SiC) ceramic. Flattened Brazilian disc specimens of ZrB2−20%SiC were prepared to conduct dynamic tensile tests using the modified Split Hopkinson pressure bar system. The tensile experiments were completed at the range of loading rates from 7.53 to 74.71 GP s−1. The tensile experimental results revealed that the zirconium diboride-silicon carbide ceramic composite is rate-sensitive in terms of the tensile strength and failure mode. The dynamic tensile strength increases linearly with the loading rate and changes from 195 MPa at 7.53 GP s−1 to 654 MPa at 74.71 GP s−1. Moreover, the dynamic tensile strength decreases with the increase in critical fracture time, which conforms to Tuler and Butcher's fracture criterion. In dynamic experiments, a high-speed camera was used to examine the tensile failure process, and fragments were collected to analyze the dynamic tensile failure mechanism. The tensile fracture mode of ZrB2−20%SiC obviously showed the sensitivity of the loading rate. The fragment size of ZrB2−20%SiC ceramic decreased but the quantity of fragments increased as the loading rate increased. 相似文献
80.
《Journal of the European Ceramic Society》2020,40(8):2828-2833
The traditional chemical vapor infiltration (CVI) method still faces massive challenge in improving the densification owing to its unavoidable bottleneck effect. Herein, laser assisted-chemical vapor infiltration (LA-CVI) was introduced to fabricate C/SiC composites with mass transfer channels. As a result, the densities of the C/SiC composites were improved due to the dense band formed during the LA-CVI process. Also, with different spacing of mass transfer channels, C/SiC composites exhibited enhanced degree of densification varying from 2.10 to 2.23 g/cm3. When the spacing of channels was 3 mm, the maximum value of flexural strength reached 528 ± 12 MPa. Additionally, micro-CT and finite element analysis were empolyed to investigate dense band and density gradient in detail. The results show that C/SiC composites prepared via LA-CVI method with suitable spacing of channels had improved density and great flexural strength. The proposed method provides a novel route for the preparation of ceramic matrix composites with high density. 相似文献